You Won’t Believe These Celebrity Duos Were Once Married

Have you ever looked at two celebrities and thought, “Wow, those two are polar opposites, I could never see them together,” and then you find out they were married at one point? Jaw. Dropped. Here is a list of celebrity duos you'll never believe were ever married.

1. Scott Foley and Jennifer Garner

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These two met on the set of Felicity in 1998 and married in 2000.

By 2003 the divorce was filed and Garner went on to date her Alias costar Michael Vartan before shacking up with Ben Affleck in 2004.

2. Drew Barrymore and Tom Green

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Drew Barrymore married comedian Tom Green in 2001. The pair starred in Charlie's Angels as well as one of Tom's own films before he filed for divorce in December of the same year.

3. Tom Cruise and Mimi Rogers

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Believe it or not, there was a pre-Nicole Kidman and Katie Holmes for Mr. Cruise. He wed actress Mimi Rogers in 1987, and their divorce was finalized just three years later.

4. Madonna and Sean Penn

Courtesy of Dave Lewis

These two married in 1985 and were divorced by 1989. No hard feelings, though, because Madonna dedicated her third album, True Blue, to Sean.

5. Kid Rock and Pamela Anderson

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Kid and Pam married in 2006 on a party yacht of all places in St. Tropez. Alas, their union was doomed to become another “celebrity marriage”, as it was over by November of that same year.

6. Ryan Reynolds and Scarlett Johansson

Courtesy of Kevin Mazur

Everyone's two biggest celebrity crushes were once joined in holy matrimony. You heard me. In September 2008, these two heartthrobs wed in a private ceremony, but alas, were not meant to be. In 2010, they announced their split and Ryan went on to marry the lovely Blake Lively.

7. Angelina Jolie and Billy Bob Thornton

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This duo met while filming Pushing Tin and married in 2000. They divorced in 2002 and Angelina took custody of their adopted son, Maddox.

8. Kim Kardashian and Damon Thomas

Courtesy of Frazer Harrison

Before her Kris Humphries and iconic Kanye era, Kim was actually married to Damon Thomas. They were married from 2000-2004.

9. Katy Perry and Russell Brand

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Pop star Katy and her beau of the time, comedian Russell Brand, tied the knot in 2010, but it was over in 14 months.

10. Wiz Khalifa and Amber Rose

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This rapper and model duo married in 2013, and, as per the trend, were promptly divorced 14 months later.

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